8,435 research outputs found
Signatures of β-sheet secondary structures in linear and two-dimensional infrared spectroscopy
Using idealized models for parallel and antiparallel β sheets, we calculate the linear and two-dimensional infrared spectra of the amide I vibration as a function of size and secondary structure. The model assumes transition–dipole coupling between the amide I oscillators in the sheet and accounts for the anharmonic nature of these oscillators. Using analytical and numerical methods, we show that the nature of the one-quantum vibrational eigenstates, which govern the linear spectrum, is, to a large extent, determined by the symmetry of the system and the relative magnitude of interstrand interactions. We also find that the eigenstates, in particular their trends with system size, depend sensitively on the secondary structure of the sheet. While in practice these differences may be difficult to distinguish in congested linear spectra, we demonstrate that they give rise to promising markers for secondary structure in the two-dimensional spectra. In particular, distinct differences occur between the spectra of parallel and antiparallel bsheets and between β hairpins and extended β sheets.
Periodic integrable systems with delta-potentials
In this paper we study root system generalizations of the quantum Bose-gas on
the circle with pair-wise delta function interactions. The underlying symmetry
structures are shown to be governed by the associated graded of Cherednik's
(suitably filtered) degenerate double affine Hecke algebra, acting by
Dunkl-type differential-reflection operators. We use Gutkin's generalization of
the equivalence between the impenetrable Bose-gas and the free Fermi-gas to
derive the Bethe ansatz equations and the Bethe ansatz eigenfunctions.Comment: 36 pages. The analysis of the propagation operator in Sections 5 and
6 is corrected and simplified. To appear in Comm. Math. Phy
Effect of Co doping and hydrostatic pressure on SrFe2As2
We report a pressure study on electron doped SrFeCoAs by
electrical-resistivity () and magnetic-susceptibility ()
experiments. Application of either external pressure or Co substitution rapidly
suppresses the spin-density wave ordering of the Fe moments and induces
superconductivity in SrFeAs. At the broad superconducting (SC)
dome in the phase diagram exhibits its maximum K at
a pressure of only GPa. In
SrFeCoAs no superconductivity is observed anymore up to 2.8
GPa. Upon increasing the Co concentration the maximum of the SC dome shifts
toward lower pressure accompanied by a decrease in the value of . Even though, superconductivity is induced by both tuning methods, Co
substitution leads to a much more robust SC state. Our study evidences that in
SrFeCoAs both, the effect of pressure and Co-substitution, have
to be considered in order to understand the SC phase-diagram and further
attests the close relationship of SrFeAs and its sister compound
BaFeAs.Comment: 6 pages, 6 figure
Observing the Spontaneous Breakdown of Unitarity
During the past decade, the experimental development of being able to create
ever larger and heavier quantum superpositions has brought the discussion of
the connection between microscopic quantum mechanics and macroscopic classical
physics back to the forefront of physical research. Under equilibrium
conditions this connection is in fact well understood in terms of the mechanism
of spontaneous symmetry breaking, while the emergence of classical dynamics can
be described within an ensemble averaged description in terms of decoherence.
The remaining realm of individual-state quantum dynamics in the thermodynamic
limit was addressed in a recent paper proposing that the unitarity of quantum
mechanical time evolution in macroscopic objects may be susceptible to a
spontaneous breakdown. Here we will discuss the implications of this theory of
spontaneous unitarity breaking for the modern experiments involving truly
macroscopic Schrodinger cat states.Comment: 4 pages, no figure
Nursing the Fatherland? Hohenzollern State Building and the Hidden Transcript of Political Resistance in Hanoverian Female Charity during the Second German Empire
In summer 1866 the Austro-Prussian struggle for supremacy in Germany erupted into open conflict. King Georg V of Hanover sided with other governments loyal to the German Confederation against Prussia, but after initially defeating Prussian forces at Langensalza, he was forced to capitulate. Two days after the battle, on June 29, 1866, the widow of the Hanoverian general Sir Georg Julius von Hartmann told her daughter in no uncertain terms how she felt about the Prussian government and its allies. In her opinion they were nothing more than "robber states” that cloaked their disregard for the Ten Commandments in sanctimonious public displays of piety. "These Protestant Jesuits,” she continued, "offend me more than the Catholic ones. You know that I am German with all my heart and love my Germany, but I cannot consider them genuine Germans anymore because they only want to make Germany Prussian.
Competition of local-moment ferromagnetism and superconductivity in Co-substituted EuFe2As2
In contrast to SrFe2As2, where only the iron possesses a magnetic moment, in
EuFe2As2 an additional large, local magnetic moment is carried by Eu2+. Like
SrFe2As2, EuFe2As2 exhibits a spin-density wave transition at high
temperatures, but in addition the magnetic moments of the Eu2+ order at around
20 K. The interplay of pressure-induced superconductivity and the Eu2+ order
leads to a behavior which is reminiscent of re-entrant superconductivity as it
was observed, for example, in the ternary Chevrel phases or in the rare-earth
nickel borocarbides. Here, we study the delicate interplay of the ordering of
the Eu2+ moments and superconductivity in EuFe1.9Co0.1As2, where application of
external pressure makes it possible to sensitively tune the ratio of the
magnetic (T_C) and the superconducting (T_{c,onset}) critical temperatures. We
find that superconductivity disappears once T_C > T_{c,onset}.Comment: 4 pages, 4 figures, submitted to the proceedings of SCES201
Quantum Diffusion on Molecular Tubes: Universal Scaling of the 1D to 2D Transition
The transport properties of disordered systems are known to depend critically
on dimensionality. We study the diffusion coefficient of a quantum particle
confined to a lattice on the surface of a tube, where it scales between the 1D
and 2D limits. It is found that the scaling relation is universal and
independent of the disorder and noise parameters, and the essential order
parameter is the ratio between the localization length in 2D and the
circumference of the tube. Phenomenological and quantitative expressions for
transport properties as functions of disorder and noise are obtained and
applied to real systems: In the natural chlorosomes found in light-harvesting
bacteria the exciton transfer dynamics is predicted to be in the 2D limit,
whereas a family of synthetic molecular aggregates is found to be in the
homogeneous limit and is independent of dimensionality.Comment: 10 pages, 6 figure
Global and regional importance of the direct dust-climate feedback.
Feedbacks between the global dust cycle and the climate system might have amplified past climate changes. Yet, it remains unclear what role the dust-climate feedback will play in future anthropogenic climate change. Here, we estimate the direct dust-climate feedback, arising from changes in the dust direct radiative effect (DRE), using a simple theoretical framework that combines constraints on the dust DRE with a series of climate model results. We find that the direct dust-climate feedback is likely in the range of -0.04 to +0.02 Wm -2 K-1, such that it could account for a substantial fraction of the total aerosol feedbacks in the climate system. On a regional scale, the direct dust-climate feedback is enhanced by approximately an order of magnitude close to major source regions. This suggests that it could play an important role in shaping the future climates of Northern Africa, the Sahel, the Mediterranean region, the Middle East, and Central Asia
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